Chin Pao Huang, Charles R. O'Melia, James J. Morgan's Aquatic chemistry: interfacial and interspecies processes PDF

By Chin Pao Huang, Charles R. O'Melia, James J. Morgan

ISBN-10: 084122921X

ISBN-13: 9780841229211

Offers finished experimental and theoretical analyses of chemical reactions in multiphase, multispecies structures. Explores the rules and purposes of floor chemistry, soil chemistry, microbiology, geochemistry, redox response, and colloid chemistry to environmental structures. Examines the influence of abiotic and biotic interfaces on chemical reactions in aquatic setting structures. comprises chapters through Werner Stumm, the founding father of aquatic chemistry.

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Giovanoli, R; Schneider, W J. Chem. Technol. BioI. 1989, 46, 115-134. 54. ; Matijevic, E. J. Colloid Interface Sci. 1979, 68, 408. 55. Luther, G. W, III Geochim. Cosmochim. Acta 1987, 51, 3193-3199. RECEIVED for review October 23, 1992. ACCEPTED revised manuscript May 24, 1993. 2 Adsorption as a Problem. in Coordination Chemistry The Concept of the Surface Complex Garrison Sposito Department of Environmental Science, Policy and Management, University of California, Berkeley, CA 94720-3110 The interfaCial aqueous coordination chemistry of natural particles, in particular their surface complexation reactions, owes much of its development to the research of Werner Stumm.

Stumm, W Geochim. Cosmochim. Acta 1986,50, 1847-1860. 22. Blum, A. ; Lasaga, A. C. ; Wiley Interscience: New York, 1987; pp 255-292. 23. Stumm, W; Wollast, R. Rev. Geophys. 1990, 28/1, 53-69. 24. ; Stumm, W Langmuir 1991, 7, 809--813. 25. Sulzberger, B. Chemistry of the Solid-Water Interface; Wiley Interscience: New York, 1992; Chapter 10. 26. Lakind, J. ; Stone, A. T. Geochim. Cosmochim. Acta 1989,53, 961-971. 27. ; Stumm, W. Langmuir 1992, 8, 1671. 28. Plummer, L. ; Wigley, T. M. ; Parkhurst, D.

E and goethite (18), forms inner-sphere surface complexes in the form of 30 AQUATIC CHEMISTRY multinuclear clusters. When Cr(III) is coprecipitated with Fe(III), isomorphic substitution of Cr(I1I) for Fe(III) occurs. ,56/s), decreases the reactivity of the oxide structure. Similar effects may be expected for Co and Ni (k_w for Co(III) = lO- l /s; Co(II) = 1O-53 /s; and Ni(II) = 1O-42/s). Mo plausibly adds polymolybdate interligating with iron comers to the oxide film. Cations. Cations like Zn2+ form binuclear complexes and reduce surface protonation.

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Aquatic chemistry: interfacial and interspecies processes by Chin Pao Huang, Charles R. O'Melia, James J. Morgan

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